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Groups > alt.usenet.kooks > #652306
| From | Friendly Neighborhood Vote Wrangler Emeritus <FNVWe@altusenetkooks.xxx> |
|---|---|
| References | <op.yd5pdbdhtm21m2@benson.localhost> <6lk5eb1n7kcteef3bhs6d63k51hj78am1r@4ax.com> |
| Subject | Re: he doesn't even know the electronegativity of oxygen |
| Message-ID | <04dfe379187b680e081e4be8fcef2bf8@dizum.com> (permalink) |
| Date | 2016-03-13 06:54 +0100 |
| Newsgroups | alt.usenet.kooks, sci.physics |
| Organization | dizum.com - The Internet Problem Provider |
Cross-posted to 2 groups.
Time to spin the kooks up again. Melt, kooks, melt. <snicker> Bite My Shiny Metal Ass (aka Shiny Tinfoil Brain), in <news:6lk5eb1n7kcteef3bhs6d63k51hj78am1r@4ax.com> did thusly jump head first into the wood chipper again: > I think fakey really does know. > Why is he so afraid of saying it? > > Hey, maybe if he holds his breath and turns blue, all the > oxygen atoms in the universe will suddenly have a +8 > electronegativity. *You* stupidly persist in k'laming me to think electronegativity is nuclear charge. I've never mentioned the nucleus in this discussion, you did. Because you don't realize you're yet again blathering on about something you know little about. You're blathering on about nuclear charge without knowing you're actually blathering on about *effective* nuclear charge, which is different for different electron orbital shells. You keep bleating about the number of protons in the nucleus as your kooky "nuclear charge" of 8, but it's not 8, in the 1s orbital it's 7.658, in the 2s orbital it's 4.492, in the 2p orbital it's 4.453. Because you didn't know the number of protons does *not* equal the effective nuclear charge of an atom. Zeff = Z - S Were you perhaps instead thinking of the atomic number, Moron? Moron?... SPNAK! > I would be impressed. Awww, I've let the moron bleat out his stupidity long enough... bend over and ready yourself for Das Boot, Shiny Tinfoil Brain. LOL Aren't you the moron who k'lames that elemental oxygen has a constant electronegativity? <https://en.wikipedia.org/wiki/Electronegativity> ================================================= As it is usually calculated, electronegativity is not a property of an atom alone, but rather a property of an atom in a molecule.[4] The property of electronegativity of an atom in a molecule is different from the electrode potential of the element, which depends on the difference in free energy of the element in its standard state and in ionic solution, and it is different from the ionization potential of the atom, and from its electron affinity; although it is related to these properties in a general way. It has been found possible to formulate an electronegativity scale of the elements by the analysis of the values of delta and delta_umlaut given by the single-bond energies. In Table 3-6 values of delta_umlaut are listed for the bonds between nonmetallic atoms whose energies are given in Table 3-4. These are obtained in the same ways as those in Table 3-3. It is seen on inspection that the values of delta_umlaut do not satisfy an additivity relation; they cannot be represented as differences of terms characteristic of the two atoms in a bond. However, the square roots of the delta_umlaut values do satisfy approximately a relation of this sort. The method just described for formulating the electronegativity scale cannot be used for the remaining elements in general because of a lack of knowledge of enthalpies of formation of their compounds as gases and of the values of single-bond energies for the elements themselves. Except for nitrogen and oxygen, which are discussed below, the elements in their standard states do not differ much in energy from states involving normal single covalent bonds between the atoms. It is the unusual stability of multiple bonds for oxygen and nitrogen, stabilizing their normal states, that often leads to negative values of the enthalpy of formation of substances. By the use of Equation 3-13 the difference in electronegativity of two elements can be calculated from the enthalpy of formation of the compounds formed by them. Table 3-8: The values given in the table refer to the common oxidation states of the elements. For some elements variation of the electronegativity with oxidation number is observed. [4] Pauling, Linus (1960). Nature of the Chemical Bond. Cornell University Press. pp. 88–107. ISBN 0-8014-0333-2. ================================================= How do you oxidize *oxygen* except with fluorine to figure out its enthalpy of formation and thus its exact electronegativity, you fecking *moron*? *No* *one* wants to formulate FOOF (O2F2) to find out the exact oxidation state of elemental oxygen. You know, FOOF, Lucifer's Gas? That shit makes *ice* explode. It makes asbestos *burn*. It reacts with gold. Hit it with a CO2 fire extinguisher, you just make it mad. So... your bleating about oxygen's electronegativity means you're bleating about an approximation, Moron. Even Pauling himself admitted that elemental electronegativity is an approximation, and thus isn't all that accurate, which is why he only presented them with single decimal accuracy. Moron. Further, oxygen's affinity for itself in forming multiple bonds means that for a lot of substances, the enthalpy of formation is negative, thus the electronegativity is dependent upon which substance oxygen is interacting with and whatever other factors contribute to or detract from that interaction. Nitrogen is the same way, nitrogen trichloride isn't unstable because of weak N-Cl bonds, but rather because nitrogen is constantly trying to reform into triple-bonded N2, with a negative enthalpy of formation and thus exothermic reaction of nitrogen trichloride. You know, Linus Pauling... the guy who developed the first accurate electronegativity scale for molecules... you think *he* might know a bit more about electronegativity than a moronic bleatfarting retard like you, Shiny Tinfoil Brain? LOL SPNAK! Why are you so stupid, Shiny Tinfoil Brain? <snicker> -- Shiny Tinfoil Brain (aka Bite My Shiny Metal Ass) didn't know: ===================================== The Euler equation is a subset of equations known as the Euler-Fourier Formulas, thus that a sinewave is a transformation of a circle (which should have been intuitive, given that generators *rotate* to create *sinusoids*); That cross correlation is used with Fourier transforms; That superposition is the same as wave interference; That wave interference works the same for standing or traveling waves; That RMS and peak-to-peak voltage are two different things; That RMS isn't a DC voltage; That 170 volt peak, 120.208 volt RMS L-N 3-phase service gives 208.207 volts RMS L-L; That 4444525800 != 4400000000 != 1; The difference between frequency and period of a sinewave; That there's no difference between 'i' and 'j' in electrical engineering, physics and control systems engineering; What a positive or negative vector is; That the vector sum of 3-phase AC constitutes a closed loop per Kirchhoff's Voltage Law, thus that the three phases sum to zero; That "mnemonic" is not spelled "mneumonic"; That his claim: "Water is tetrahedral. It actually has 4 poles, 2 positive and 2 negative." is nonsense from a blathering moron. That water does not have negative poles. The oxygen has an electronegativity of 8+, the hydrogens 1+. That the term "electronegativity" denotes a *positive* nucleal charge. What the definition of the word "equivalent" is. That digital voltmeters do indeed take discrete instantaneous samples. That the atmosphere (and the gaseous phase water within the atmosphere) does indeed follow the Ideal Gas Law to within 1.337842% margin of error *worst* *case* at 70 F. That the square of the instantaneous sample of peak-to-peak voltage of a peak-voltage sinewave is an offset sinewave, thus its average does *not* equal zero, as Shiny Tinfoil Brain k'lames. That the Ideal Gas Law does not require an ideal gas because it takes into account molar volume. That "within 10% error" does not equal "10% error". That water can be plasmized. That atomic number does not equal effective nuclear charge. That nuclear charge does not equal effective nuclear charge. And the moron continues to demonstrate his inability to read a graph. ===================================== SPNAK! <snicker>
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he doesn't even know the electronegativity of oxygen "\"Fakey's\" dogwhistle holder living at 5907 Stanton Ave., Pittsburgh, PA (aka Teh Mop Jockey), socked up as 5907 Stanton Avenue, Pittsburgh, PA 15206-2117" <root@127.0.0.1> - 2016-03-11 05:42 -0500
Re: he doesn't even know the electronegativity of oxygen Bite My Shiny Metal Ass <bender@the.future> - 2016-03-11 22:16 +0800
Re: he doesn't even know the electronegativity of oxygen snipeco.2@gmail.com (Sn!pe) - 2016-03-11 15:06 +0000
Re: he doesn't even know the electronegativity of oxygen Bite My Shiny Metal Ass <bender@the.future> - 2016-03-12 00:47 +0800
Re: he doesn't even know the electronegativity of oxygen Friendly Neighborhood Vote Wrangler Emeritus <FNVWe@altusenetkooks.xxx> - 2016-03-13 06:54 +0100
Re: he doesn't even know the electronegativity of oxygen Bite My Shiny Metal Ass <bender@the.future> - 2016-03-13 16:01 +0800
Re: he doesn't even know the electronegativity of oxygen Friendly Neighborhood Vote Wrangler Emeritus <FNVWe@altusenetkooks.xxx> - 2016-03-14 05:12 +0100
Re: he doesn't even know the electronegativity of oxygen Bite My Shiny Metal Ass <bender@the.future> - 2016-03-14 14:35 +0800
Re: he doesn't even know the electronegativity of oxygen Friendly Neighborhood Vote Wrangler Emeritus <FNVWe@altusenetkooks.xxx> - 2016-03-14 16:03 +0100
Re: he doesn't even know the electronegativity of oxygen Skeeter <skeet@invalid.invalid> - 2016-03-13 03:09 -0600
Re: he doesn't even know the electronegativity of oxygen Chicken F*cker DOW #4 <willaim.jillians649@btinternet.com> - 2016-03-12 03:52 +0000
Re: he doesn't even know the electronegativity of oxygen Bite My Shiny Metal Ass <bender@the.future> - 2016-03-12 15:46 +0800
Re: he doesn't even know the electronegativity of oxygen Chicken F*cker DOW #4 <willaim.jillians649@btinternet.com> - 2016-03-12 08:19 +0000
Re: he doesn't even know the electronegativity of oxygen Bite My Shiny Metal Ass <bender@the.future> - 2016-03-12 16:33 +0800
Re: he doesn't even know the electronegativity of oxygen Chicken F*cker DOW #4 <willaim.jillians649@btinternet.com> - 2016-03-12 08:53 +0000
Re: he doesn't even know the electronegativity of oxygen Bite My Shiny Metal Ass <bender@the.future> - 2016-03-12 17:12 +0800
Re: he doesn't even know the electronegativity of oxygen Chicken F*cker DOW #4 <willaim.jillians649@btinternet.com> - 2016-03-12 09:16 +0000
Re: he doesn't even know the electronegativity of oxygen Bite My Shiny Metal Ass <bender@the.future> - 2016-03-13 16:53 +0800
Re: he doesn't even know the electronegativity of oxygen Skeeter <skeet@invalid.invalid> - 2016-03-13 03:18 -0600
Re: he doesn't even know the electronegativity of oxygen Psychotic Chicken <Bill@btinternet.com> - 2016-03-15 10:18 +0000
he doesn't even know the electronegativity of oxygen Friendly Neighborhood Vote Wrangler Emeritus <FNVWe@altusenetkooks.xxx> - 2016-03-22 01:34 +0100
Re: he doesn't even know the electronegativity of oxygen Janithor <Janithor@comcast.net> - 2016-03-21 17:52 -0700
Re: he doesn't even know the electronegativity of oxygen "%" <persent@gmail.com> - 2016-03-21 18:06 -0700
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